Enhancement of aromatics from catalytic pyrolysis of yellow poplar: Role of hydrogen and methane decomposition.
Identifieur interne : 000427 ( Main/Exploration ); précédent : 000426; suivant : 000428Enhancement of aromatics from catalytic pyrolysis of yellow poplar: Role of hydrogen and methane decomposition.
Auteurs : Surendar Moogi [Corée du Sud] ; Jungho Jae [Corée du Sud] ; Hari Prasad Reddy Kannapu [Corée du Sud] ; Ashfaq Ahmed [Corée du Sud] ; Eun Duck Park [Corée du Sud] ; Young-Kwon Park [Corée du Sud]Source :
- Bioresource technology [ 1873-2976 ] ; 2020.
Descripteurs français
- KwdFr :
- MESH :
English descriptors
- KwdEn :
- MESH :
- chemical : Hydrogen, Methane.
- Biomass, Catalysis, Hot Temperature, Liriodendron, Pyrolysis.
Abstract
The present study examined the effects of the pyrolysis environment on BTEX (benzene, toluene, ethylbenzene, and xylenes) production in the catalytic upgrading of yellow poplar pyrolysis vapors. Three different gas environments, N2, CH4, and pre-decomposed CH4 stream (10 wt%-Ni/5 wt%-La2O3-5 wt% CeO2-Al2O3), which is a mixture of H2 (55.62%) and CH4, were studied using two types of zeolite catalysts, HZSM-5, and 1 wt% Ga/HZSM-5. The BTEX yields were enhanced linearly in the order N2 < CH4 < CH4 ex-situ decomposition. The highest BTEX yield of 9.58 wt% was obtained under the CH4 ex-situ decomposition environment over 1 wt% Ga/HZSM-5. The methane and hydrocarbons derived from biomass were activated on highly dispersed (GaO)+ sites and transformed smoothly to BTEX by aromatization on the BrØnsted acid sites of Ga/HZSM-5. The hydrogen produced from methane decomposition also assisted in aromatics production through the hydrodeoxygenation of methoxyphenols, guaiacols and catechols.
DOI: 10.1016/j.biortech.2020.123835
PubMed: 32693345
Affiliations:
Links toward previous steps (curation, corpus...)
Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Enhancement of aromatics from catalytic pyrolysis of yellow poplar: Role of hydrogen and methane decomposition.</title><author><name sortKey="Moogi, Surendar" sort="Moogi, Surendar" uniqKey="Moogi S" first="Surendar" last="Moogi">Surendar Moogi</name><affiliation wicri:level="1"><nlm:affiliation>School of Environmental Engineering, University of Seoul, Seoul 02504, Republic of Korea.</nlm:affiliation><country xml:lang="fr">Corée du Sud</country><wicri:regionArea>School of Environmental Engineering, University of Seoul, Seoul 02504</wicri:regionArea><placeName><settlement type="city">Séoul</settlement><region type="capital">Région capitale de Séoul</region></placeName></affiliation></author><author><name sortKey="Jae, Jungho" sort="Jae, Jungho" uniqKey="Jae J" first="Jungho" last="Jae">Jungho Jae</name><affiliation wicri:level="1"><nlm:affiliation>School of Chemical and Biomolecular Engineering, Pusan National University, Busan 46241, Republic of Korea.</nlm:affiliation><country xml:lang="fr">Corée du Sud</country><wicri:regionArea>School of Chemical and Biomolecular Engineering, Pusan National University, Busan 46241</wicri:regionArea><wicri:noRegion>Busan 46241</wicri:noRegion></affiliation></author><author><name sortKey="Kannapu, Hari Prasad Reddy" sort="Kannapu, Hari Prasad Reddy" uniqKey="Kannapu H" first="Hari Prasad Reddy" last="Kannapu">Hari Prasad Reddy Kannapu</name><affiliation wicri:level="1"><nlm:affiliation>School of Environmental Engineering, University of Seoul, Seoul 02504, Republic of Korea.</nlm:affiliation><country xml:lang="fr">Corée du Sud</country><wicri:regionArea>School of Environmental Engineering, University of Seoul, Seoul 02504</wicri:regionArea><placeName><settlement type="city">Séoul</settlement><region type="capital">Région capitale de Séoul</region></placeName></affiliation></author><author><name sortKey="Ahmed, Ashfaq" sort="Ahmed, Ashfaq" uniqKey="Ahmed A" first="Ashfaq" last="Ahmed">Ashfaq Ahmed</name><affiliation wicri:level="1"><nlm:affiliation>School of Environmental Engineering, University of Seoul, Seoul 02504, Republic of Korea.</nlm:affiliation><country xml:lang="fr">Corée du Sud</country><wicri:regionArea>School of Environmental Engineering, University of Seoul, Seoul 02504</wicri:regionArea><placeName><settlement type="city">Séoul</settlement><region type="capital">Région capitale de Séoul</region></placeName></affiliation></author><author><name sortKey="Park, Eun Duck" sort="Park, Eun Duck" uniqKey="Park E" first="Eun Duck" last="Park">Eun Duck Park</name><affiliation wicri:level="1"><nlm:affiliation>Department of Chemical Engineering and Department of Energy Systems Research, Ajou University, Suwon 16499, Republic of Korea.</nlm:affiliation><country xml:lang="fr">Corée du Sud</country><wicri:regionArea>Department of Chemical Engineering and Department of Energy Systems Research, Ajou University, Suwon 16499</wicri:regionArea><wicri:noRegion>Suwon 16499</wicri:noRegion></affiliation></author><author><name sortKey="Park, Young Kwon" sort="Park, Young Kwon" uniqKey="Park Y" first="Young-Kwon" last="Park">Young-Kwon Park</name><affiliation wicri:level="1"><nlm:affiliation>School of Environmental Engineering, University of Seoul, Seoul 02504, Republic of Korea. Electronic address: catalica@uos.ac.kr.</nlm:affiliation><country xml:lang="fr">Corée du Sud</country><wicri:regionArea>School of Environmental Engineering, University of Seoul, Seoul 02504</wicri:regionArea><placeName><settlement type="city">Séoul</settlement><region type="capital">Région capitale de Séoul</region></placeName></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PubMed</idno><date when="2020">2020</date><idno type="RBID">pubmed:32693345</idno><idno type="pmid">32693345</idno><idno type="doi">10.1016/j.biortech.2020.123835</idno><idno type="wicri:Area/Main/Corpus">000181</idno><idno type="wicri:explorRef" wicri:stream="Main" wicri:step="Corpus" wicri:corpus="PubMed">000181</idno><idno type="wicri:Area/Main/Curation">000181</idno><idno type="wicri:explorRef" wicri:stream="Main" wicri:step="Curation">000181</idno><idno type="wicri:Area/Main/Exploration">000181</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">Enhancement of aromatics from catalytic pyrolysis of yellow poplar: Role of hydrogen and methane decomposition.</title><author><name sortKey="Moogi, Surendar" sort="Moogi, Surendar" uniqKey="Moogi S" first="Surendar" last="Moogi">Surendar Moogi</name><affiliation wicri:level="1"><nlm:affiliation>School of Environmental Engineering, University of Seoul, Seoul 02504, Republic of Korea.</nlm:affiliation><country xml:lang="fr">Corée du Sud</country><wicri:regionArea>School of Environmental Engineering, University of Seoul, Seoul 02504</wicri:regionArea><placeName><settlement type="city">Séoul</settlement><region type="capital">Région capitale de Séoul</region></placeName></affiliation></author><author><name sortKey="Jae, Jungho" sort="Jae, Jungho" uniqKey="Jae J" first="Jungho" last="Jae">Jungho Jae</name><affiliation wicri:level="1"><nlm:affiliation>School of Chemical and Biomolecular Engineering, Pusan National University, Busan 46241, Republic of Korea.</nlm:affiliation><country xml:lang="fr">Corée du Sud</country><wicri:regionArea>School of Chemical and Biomolecular Engineering, Pusan National University, Busan 46241</wicri:regionArea><wicri:noRegion>Busan 46241</wicri:noRegion></affiliation></author><author><name sortKey="Kannapu, Hari Prasad Reddy" sort="Kannapu, Hari Prasad Reddy" uniqKey="Kannapu H" first="Hari Prasad Reddy" last="Kannapu">Hari Prasad Reddy Kannapu</name><affiliation wicri:level="1"><nlm:affiliation>School of Environmental Engineering, University of Seoul, Seoul 02504, Republic of Korea.</nlm:affiliation><country xml:lang="fr">Corée du Sud</country><wicri:regionArea>School of Environmental Engineering, University of Seoul, Seoul 02504</wicri:regionArea><placeName><settlement type="city">Séoul</settlement><region type="capital">Région capitale de Séoul</region></placeName></affiliation></author><author><name sortKey="Ahmed, Ashfaq" sort="Ahmed, Ashfaq" uniqKey="Ahmed A" first="Ashfaq" last="Ahmed">Ashfaq Ahmed</name><affiliation wicri:level="1"><nlm:affiliation>School of Environmental Engineering, University of Seoul, Seoul 02504, Republic of Korea.</nlm:affiliation><country xml:lang="fr">Corée du Sud</country><wicri:regionArea>School of Environmental Engineering, University of Seoul, Seoul 02504</wicri:regionArea><placeName><settlement type="city">Séoul</settlement><region type="capital">Région capitale de Séoul</region></placeName></affiliation></author><author><name sortKey="Park, Eun Duck" sort="Park, Eun Duck" uniqKey="Park E" first="Eun Duck" last="Park">Eun Duck Park</name><affiliation wicri:level="1"><nlm:affiliation>Department of Chemical Engineering and Department of Energy Systems Research, Ajou University, Suwon 16499, Republic of Korea.</nlm:affiliation><country xml:lang="fr">Corée du Sud</country><wicri:regionArea>Department of Chemical Engineering and Department of Energy Systems Research, Ajou University, Suwon 16499</wicri:regionArea><wicri:noRegion>Suwon 16499</wicri:noRegion></affiliation></author><author><name sortKey="Park, Young Kwon" sort="Park, Young Kwon" uniqKey="Park Y" first="Young-Kwon" last="Park">Young-Kwon Park</name><affiliation wicri:level="1"><nlm:affiliation>School of Environmental Engineering, University of Seoul, Seoul 02504, Republic of Korea. Electronic address: catalica@uos.ac.kr.</nlm:affiliation><country xml:lang="fr">Corée du Sud</country><wicri:regionArea>School of Environmental Engineering, University of Seoul, Seoul 02504</wicri:regionArea><placeName><settlement type="city">Séoul</settlement><region type="capital">Région capitale de Séoul</region></placeName></affiliation></author></analytic><series><title level="j">Bioresource technology</title><idno type="eISSN">1873-2976</idno><imprint><date when="2020" type="published">2020</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Biomass (MeSH)</term><term>Catalysis (MeSH)</term><term>Hot Temperature (MeSH)</term><term>Hydrogen (MeSH)</term><term>Liriodendron (MeSH)</term><term>Methane (MeSH)</term><term>Pyrolysis (MeSH)</term></keywords><keywords scheme="KwdFr" xml:lang="fr"><term>Biomasse (MeSH)</term><term>Catalyse (MeSH)</term><term>Hydrogène (MeSH)</term><term>Liriodendron (MeSH)</term><term>Méthane (MeSH)</term><term>Pyrolyse (MeSH)</term><term>Température élevée (MeSH)</term></keywords><keywords scheme="MESH" type="chemical" xml:lang="en"><term>Hydrogen</term><term>Methane</term></keywords><keywords scheme="MESH" xml:lang="en"><term>Biomass</term><term>Catalysis</term><term>Hot Temperature</term><term>Liriodendron</term><term>Pyrolysis</term></keywords><keywords scheme="MESH" xml:lang="fr"><term>Biomasse</term><term>Catalyse</term><term>Hydrogène</term><term>Liriodendron</term><term>Méthane</term><term>Pyrolyse</term><term>Température élevée</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The present study examined the effects of the pyrolysis environment on BTEX (benzene, toluene, ethylbenzene, and xylenes) production in the catalytic upgrading of yellow poplar pyrolysis vapors. Three different gas environments, N<sub>2</sub>, CH<sub>4</sub>, and pre-decomposed CH<sub>4</sub> stream (10 wt%-Ni/5 wt%-La<sub>2</sub>O<sub>3</sub>-5 wt% CeO<sub>2</sub>-Al<sub>2</sub>O<sub>3</sub>), which is a mixture of H<sub>2</sub> (55.62%) and CH<sub>4</sub>, were studied using two types of zeolite catalysts, HZSM-5, and 1 wt% Ga/HZSM-5. The BTEX yields were enhanced linearly in the order N<sub>2</sub> < CH<sub>4</sub> < CH<sub>4</sub> ex-situ decomposition. The highest BTEX yield of 9.58 wt% was obtained under the CH<sub>4</sub> ex-situ decomposition environment over 1 wt% Ga/HZSM-5. The methane and hydrocarbons derived from biomass were activated on highly dispersed (GaO)<sup>+</sup> sites and transformed smoothly to BTEX by aromatization on the BrØnsted acid sites of Ga/HZSM-5. The hydrogen produced from methane decomposition also assisted in aromatics production through the hydrodeoxygenation of methoxyphenols, guaiacols and catechols.</div></front></TEI><pubmed><MedlineCitation Status="MEDLINE" IndexingMethod="Automated" Owner="NLM"><PMID Version="1">32693345</PMID><DateCompleted><Year>2020</Year><Month>08</Month><Day>19</Day></DateCompleted><DateRevised><Year>2020</Year><Month>08</Month><Day>19</Day></DateRevised><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1873-2976</ISSN><JournalIssue CitedMedium="Internet"><Volume>315</Volume><PubDate><Year>2020</Year><Month>Nov</Month></PubDate></JournalIssue><Title>Bioresource technology</Title><ISOAbbreviation>Bioresour Technol</ISOAbbreviation></Journal><ArticleTitle>Enhancement of aromatics from catalytic pyrolysis of yellow poplar: Role of hydrogen and methane decomposition.</ArticleTitle><Pagination><MedlinePgn>123835</MedlinePgn></Pagination><ELocationID EIdType="pii" ValidYN="Y">S0960-8524(20)31107-X</ELocationID><ELocationID EIdType="doi" ValidYN="Y">10.1016/j.biortech.2020.123835</ELocationID><Abstract><AbstractText>The present study examined the effects of the pyrolysis environment on BTEX (benzene, toluene, ethylbenzene, and xylenes) production in the catalytic upgrading of yellow poplar pyrolysis vapors. Three different gas environments, N<sub>2</sub>, CH<sub>4</sub>, and pre-decomposed CH<sub>4</sub> stream (10 wt%-Ni/5 wt%-La<sub>2</sub>O<sub>3</sub>-5 wt% CeO<sub>2</sub>-Al<sub>2</sub>O<sub>3</sub>), which is a mixture of H<sub>2</sub> (55.62%) and CH<sub>4</sub>, were studied using two types of zeolite catalysts, HZSM-5, and 1 wt% Ga/HZSM-5. The BTEX yields were enhanced linearly in the order N<sub>2</sub> < CH<sub>4</sub> < CH<sub>4</sub> ex-situ decomposition. The highest BTEX yield of 9.58 wt% was obtained under the CH<sub>4</sub> ex-situ decomposition environment over 1 wt% Ga/HZSM-5. The methane and hydrocarbons derived from biomass were activated on highly dispersed (GaO)<sup>+</sup> sites and transformed smoothly to BTEX by aromatization on the BrØnsted acid sites of Ga/HZSM-5. The hydrogen produced from methane decomposition also assisted in aromatics production through the hydrodeoxygenation of methoxyphenols, guaiacols and catechols.</AbstractText><CopyrightInformation>Copyright © 2020 Elsevier Ltd. All rights reserved.</CopyrightInformation></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Moogi</LastName><ForeName>Surendar</ForeName><Initials>S</Initials><AffiliationInfo><Affiliation>School of Environmental Engineering, University of Seoul, Seoul 02504, Republic of Korea.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Jae</LastName><ForeName>Jungho</ForeName><Initials>J</Initials><AffiliationInfo><Affiliation>School of Chemical and Biomolecular Engineering, Pusan National University, Busan 46241, Republic of Korea.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Kannapu</LastName><ForeName>Hari Prasad Reddy</ForeName><Initials>HPR</Initials><AffiliationInfo><Affiliation>School of Environmental Engineering, University of Seoul, Seoul 02504, Republic of Korea.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Ahmed</LastName><ForeName>Ashfaq</ForeName><Initials>A</Initials><AffiliationInfo><Affiliation>School of Environmental Engineering, University of Seoul, Seoul 02504, Republic of Korea.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Park</LastName><ForeName>Eun Duck</ForeName><Initials>ED</Initials><AffiliationInfo><Affiliation>Department of Chemical Engineering and Department of Energy Systems Research, Ajou University, Suwon 16499, Republic of Korea.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Park</LastName><ForeName>Young-Kwon</ForeName><Initials>YK</Initials><AffiliationInfo><Affiliation>School of Environmental Engineering, University of Seoul, Seoul 02504, Republic of Korea. Electronic address: catalica@uos.ac.kr.</Affiliation></AffiliationInfo></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2020</Year><Month>07</Month><Day>15</Day></ArticleDate></Article><MedlineJournalInfo><Country>England</Country><MedlineTA>Bioresour Technol</MedlineTA><NlmUniqueID>9889523</NlmUniqueID><ISSNLinking>0960-8524</ISSNLinking></MedlineJournalInfo><ChemicalList><Chemical><RegistryNumber>7YNJ3PO35Z</RegistryNumber><NameOfSubstance UI="D006859">Hydrogen</NameOfSubstance></Chemical><Chemical><RegistryNumber>OP0UW79H66</RegistryNumber><NameOfSubstance UI="D008697">Methane</NameOfSubstance></Chemical></ChemicalList><CitationSubset>IM</CitationSubset><MeshHeadingList><MeshHeading><DescriptorName UI="D018533" MajorTopicYN="N">Biomass</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D002384" MajorTopicYN="N">Catalysis</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D006358" MajorTopicYN="N">Hot Temperature</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D006859" MajorTopicYN="N">Hydrogen</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D031567" MajorTopicYN="Y">Liriodendron</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D008697" MajorTopicYN="N">Methane</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D000077319" MajorTopicYN="Y">Pyrolysis</DescriptorName></MeshHeading></MeshHeadingList><KeywordList Owner="NOTNLM"><Keyword MajorTopicYN="N">Aromatics</Keyword><Keyword MajorTopicYN="N">CH(4) decomposition</Keyword><Keyword MajorTopicYN="N">Catalytic co-pyrolysis</Keyword><Keyword MajorTopicYN="N">Ga/HZSM-5</Keyword><Keyword MajorTopicYN="N">Yellow poplar</Keyword></KeywordList><CoiStatement>Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.</CoiStatement></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="received"><Year>2020</Year><Month>05</Month><Day>26</Day></PubMedPubDate><PubMedPubDate PubStatus="revised"><Year>2020</Year><Month>07</Month><Day>10</Day></PubMedPubDate><PubMedPubDate PubStatus="accepted"><Year>2020</Year><Month>07</Month><Day>10</Day></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2020</Year><Month>7</Month><Day>22</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2020</Year><Month>8</Month><Day>20</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2020</Year><Month>7</Month><Day>22</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">32693345</ArticleId><ArticleId IdType="pii">S0960-8524(20)31107-X</ArticleId><ArticleId IdType="doi">10.1016/j.biortech.2020.123835</ArticleId></ArticleIdList></PubmedData></pubmed><affiliations><list><country><li>Corée du Sud</li></country><region><li>Région capitale de Séoul</li></region><settlement><li>Séoul</li></settlement></list><tree><country name="Corée du Sud"><region name="Région capitale de Séoul"><name sortKey="Moogi, Surendar" sort="Moogi, Surendar" uniqKey="Moogi S" first="Surendar" last="Moogi">Surendar Moogi</name></region><name sortKey="Ahmed, Ashfaq" sort="Ahmed, Ashfaq" uniqKey="Ahmed A" first="Ashfaq" last="Ahmed">Ashfaq Ahmed</name><name sortKey="Jae, Jungho" sort="Jae, Jungho" uniqKey="Jae J" first="Jungho" last="Jae">Jungho Jae</name><name sortKey="Kannapu, Hari Prasad Reddy" sort="Kannapu, Hari Prasad Reddy" uniqKey="Kannapu H" first="Hari Prasad Reddy" last="Kannapu">Hari Prasad Reddy Kannapu</name><name sortKey="Park, Eun Duck" sort="Park, Eun Duck" uniqKey="Park E" first="Eun Duck" last="Park">Eun Duck Park</name><name sortKey="Park, Young Kwon" sort="Park, Young Kwon" uniqKey="Park Y" first="Young-Kwon" last="Park">Young-Kwon Park</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Bois/explor/PoplarV1/Data/Main/Exploration
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000427 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 000427 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Bois
|area= PoplarV1
|flux= Main
|étape= Exploration
|type= RBID
|clé= pubmed:32693345
|texte= Enhancement of aromatics from catalytic pyrolysis of yellow poplar: Role of hydrogen and methane decomposition.
}}
Pour générer des pages wiki
HfdIndexSelect -h $EXPLOR_AREA/Data/Main/Exploration/RBID.i -Sk "pubmed:32693345" \
| HfdSelect -Kh $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd \
| NlmPubMed2Wicri -a PoplarV1
| This area was generated with Dilib version V0.6.37. |  |